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Sunday, May 3, 2020 | History

4 edition of Ion exchange and solvent extraction of metal complexes found in the catalog.

Ion exchange and solvent extraction of metal complexes

Yizhak Marcus

Ion exchange and solvent extraction of metal complexes

  • 192 Want to read
  • 6 Currently reading

Published by Wiley-Interscience in Chichester .
Written in English

    Subjects:
  • Metals.,
  • Extraction (Chemistry),
  • Ion exchange.

  • Edition Notes

    Statementby Y. Marcus and A. S. Kertes.
    ContributionsKertes, A. S.
    The Physical Object
    Paginationxi,1037p. :
    Number of Pages1037
    ID Numbers
    Open LibraryOL22642689M
    ISBN 100471568589

    Ion exchange usually describes a processes of purification of aqueous solutions using solid polymeric ion exchange precisely, the term encompasses a large variety of processes where ions are exchanged between two electrolytes. Aside from its use to purify drinking water, the technique is widely applied for purification and separation of a variety of industrially and . "The contents of this volume were originally published in Solvent extraction and ion exchange, vol no. 1, , and vol no. 4, "--Title page verso. Waste Waters and Technological Solutions from Polyvalent Metal Ions / T Properties and Application of Ion Exchanger Complexes / V. D. Kopylova --Diffusional Model for. After the stripping operation final metal recovery takes place from the aqueous solution. The recovery of metal directly from the loaded organic phase is also possible, but, currently not commercially in use. Because the solvent extraction process resembles metal extraction with solid ion exchange resins, it is sometimes called liquid ion exchange. The extraction of thorium(IV) from nitric acid solutions by di-n-butyl sulfoxide (DBSO) in xylene has been investigated as a function of acid, extractant and the metal concentration. The effect of contact time and diverse ions on the extraction has been examined. Phosphate, fluoride, oxalate and perchlorate reduce the extraction to some by:


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Ion exchange and solvent extraction of metal complexes by Yizhak Marcus Download PDF EPUB FB2

Bruce Moyer has 30 years of experience in research and development on solvent extraction and ion exchange, focusing on radionuclide separations for environmental and waste cleanup, nuclear fuel cycles, and national-security applications in the USDOE complex.5/5(1).

book: ion exchange and solvent extraction of metal complexes. Good. Ion exchange and solvent extraction of metal complexes (ExLib) by Marcus, Y. Binding: Paperback. Weight: Lbs. Product Group: Book. Istextbook: No. Special Attributes: Ex-Library.

A copy that has been read, but remains in clean condition. All pages are intact, and the cover is Ion exchange and solvent extraction of metal complexes book.

The spine may show signs of Range: $ - $6, Bruce Moyer has 30 years of experience in research and development on solvent extraction and ion exchange, focusing on radionuclide separations for environmental and waste cleanup, nuclear fuel Ion exchange and solvent extraction of metal complexes book, and national-security applications in the USDOE complex.

Moyer leads the Chemical Separations Group of ORNL’s Chemical Science Division. Ion Exchange and Solvent Extraction of Metal Complexes free energy function halides HClO4 higher HNO3 hydrocarbons hydrochloric acid hydrogen bonding increases Inorg interaction ion exchange ion-pairs ionic ketone Khim ligand ligand concentration measurements metal complexes metal ions Ion Exchange and Solvent Extraction of Metal.

Chapter 2 expands the subject of ion-pair recognition to introduce outer-sphere recognition of metal complexes. Ion exchange and solvent extraction of metal complexes book Chapter 3 reviews the literature on calixarenes as extraction reagents for metal ions.

Chapter 4 extends the utility of this chemistry, describing the Ion exchange and solvent extraction of metal complexes book of calixarenes for the extraction of biomolecules. Ion Exchange and Solvent Extraction: A Series of Advances, Volume 22 provides a focused review of new materials and new processes that have developed and are rapidly growing.

It describes cutting-edge research and practices in the use of ion exchange for building a cleaner, sustainable world and provides thoughtful insights on what ion exchange Cited by: 1. Ion Exchange and Solvent Extraction of Metal Complexes.Y.

Marcus and A. cience (Wiley), New York, xii + pp., illus. $   Ion Exchange and Solvent Extraction: A Series of Advances, Volume 15 complex component concentration constant containing continuous copper cost depends determined developed diameter dispersion drop effect efficiency energy entrainment equilibrium equipment experiments expetimenral feed fiber Figure flow rate flow sheet flux function given 3/5(1).

Ion exchange ; Metal ion exchanged into organic phase, ion transfer in aqueous phase ; Use of organic soluble acid ; i.e., alkyl phosphinic acid (R2PO2H) Ion pair extraction ; Charged metal complex with extractant of opposite charge ; i.e., Quaternary ammonium salt with anionic actinide nitrate ; 5 (CH3CH2)2O Diethyl ether.

The book begins with a discussion of the nature and definition of SC and its general use in the design of novel SX reagents. Chapter 2 expands the subject of ion-pair recognition to introduce outer-sphere recognition of metal complexes.

Chapter 3 reviews the literature on calixarenes as extraction reagents for metal : $ Ion Exchange and Solvent Extraction: A Series of Advances, Volume 17 1st Edition. Yitzhak Marcus, Arup K. SenGupta J Volume 17 in the Ion Exchange and Solvent Extraction series represents the vanguard of research on solvent extraction.

It covers the principles of electrolyte extraction and other subjects of increasing interest to the field. Separations and partitioning can be exceptionally complex with competing solvent extraction, cation, anion and sacrificial ion exchange mechanisms are.

Selective Extraction of Americium from Curium and the Lanthanides by the Lipophilic Ligand CyMe 4 BTPhen Dissolved in Aliquat Nitrate Ionic Liquid.

Published online: 21 Jan Gamma Radiolysis of TODGA and CyMe 4 BTPhen in the Ionic Liquid Tri- n -Octylmethylammonium Nitrate. Published online: 20 Jan See all volumes and issues. Browse the list of issues and latest articles from Solvent Extraction and Ion Exchange.

List of issues Latest articles Volume 38 Volume 37 Volume 36 Volume 35 Volume 34 Volume 33 Volume 32 Volume 31 Volume 30 Volume 29 Volume 28 Volume 27 Y. Marcus und A. Kertes: Ion Exchange and Solvent Extraction of Metal Complexes.

Interscience Publishers, John Wiley & Sons, New York, London, Sydney Seiten. Preis: s H. Specker. Search for more papers by this author.

Specker. Search for more papers by this : H. Specker. Current advances and results in ion exchange and solvent extraction are explained and procedures for implementation and scale-up of industrial extraction processes are presented.

Screening, design, and construction of new solvents by computer-aided molecular design are discussed, including examples of interactive, combinatorial, construct-and. Now in its 20 th volume, Ion Exchange and Solvent Extraction: A Series of Advances chronicles the ongoing changes that drive innovation in this important field.

Beginning with a review of research studies that show how functionalized ion exchange polymers serve as supports to stabilize metal nanoparticles (MNPs) without forming larger than nano.

Ion Exchange and Solvent Extraction. This volume will capture transformational changes in both the chemistry and engineering side of solvent extraction, creating new directions and deepening our understanding of the structure and dynamics of liquid-liquid systems from the molecular- to nano- to meso- to : Bruce A Moyer.

The applications of solvent extraction (SX) and liquid membranes (LM) span chemistry, metallurgy, hydrometallurgy, chemical/mineral processing, and waste treatment—making it difficult to find a single resource that encompasses fundamentals as well as.

Ionic sites, which give the polymer desired ion exchange properties, are added to the. polymer network by one or more chemical reactions. For example, strong-acid cation. exchange resins are prepared by sulfonating the benzene rings in the polymer. Proton transfer through hydrogen or coordinate-bonded intermediates leads to the formation of a classical ion exchange complex.

Different aspects of the nature of H-bonded complexes and proton transfer are also covered in the review. explaining qualitatively some mechanisms of metal solvent extraction, including the dual extraction behavior. Marcus und A. Kertes: Ion Exchange and Solvent Extraction of Metal cience Publishers, John Wiley & Sons, New York, London, Sydney Author: H.

Specker. Sole K.C. () The Evolution of Cobalt–Nickel Separation and Purification Technologies: Fifty Years of Solvent Extraction and Ion Exchange. In: Davis B. et al. (eds) Extraction The Minerals, Metals & Materials : Kathryn C. Sole. Find Ion Exchange and Solvent Extraction of Metal Complexes by at over 30 bookstores.

Buy, rent or sell. Ion Exchange and Solvent Extraction: Supramolecular Aspects of Solvent Exchange Volume 21 Book Gloe, Karsten ; Tasker, Peter A ; Oshima, Tatsuya ; Preface The theme of supramolecular chemistry (SC), entailing the organization of multiple species through noncovalent interactions, has permeated virtually all aspects of chemical endeavor over the.

Ion exchange and solvent extraction of metal complexes. London, New York [etc.] Wiley-Interscience, (OCoLC) Material Type: Internet resource: Document Type: Book, Internet Resource: All Authors / Contributors: Y Marcus; A S Kertes. METAL-CHLORIDE COMPLEXES OF TRANSITION-METALS AND ACTINIDES The low solubility of silver chloride in water, or even in chloride Jolutions where silver(I) forms complex chloride anions, has probably discouraged its study by ion exchange and solvent extraction methods, although they are well suited for the study of tracer by: Thus in the extraction of uranyl nitarate with isobutyl alcohol, the extractable complex is probably UO2(BuOH)6.(NO3)2 in which the coordinated solvent molecules contribute both to the size of cation and the resemblance of the complex to the solvent [84].File Size: KB.

Happy reading Ion Exchange & Solvent Extraction, Volume 15 (Ion Exchange and Solvent Extraction) Bookeveryone. Download file Free Book PDF Ion Exchange & Solvent Extraction, Volume 15 (Ion Exchange and Solvent Extraction) at Complete PDF Library. This Book have some digital formats such us:paperbook, ebook, kindle, epub, fb2 and another formats.

Liquid–liquid extraction (LLE), also known as solvent extraction and partitioning, is a method to separate compounds or metal complexes, based on their relative solubilities in two different immiscible liquids, usually water (polar) and an organic solvent (non-polar).

Among different techniques used for removal of high concentrations of heavy metals, precipitation-filtration, ion exchange, reverse osmosis, oxidation-reduction, solvent extraction, as well as membrane separation should be mentioned (Hubicki,et al.

; Dąbrowski et al. However, some of the wastes contain substances such as organics Cited by: and carriers. Ion exchange, solvent extraction, and solid-phase extraction separation techniques, for example, are highly dependent upon the oxidation state of the analytes.

Moreover, most radiochemical procedures involve the addition of a carrier or isotope tracer. There must be. Besides solvent extraction, novel separation techniques with liquid membrane, microemulsion and reversed micelles are also presented.

This book will introduce the biochemical engineer and process engineer to the recovery of products from complex cultivation broths by modern techniques of solvent extraction and help them with process design. Major approaches using SC principles are outlined and illustrated.

Chapter 2 expands upon the theme of ion-pair recognition and introduces outer-sphere recognition of metal complexes, a novel idea with the potential for structural control of solvation, casting a new light on solvent. Product Information.

Presenting key advancements in the areas of ion exchange and solvent extraction on par with the high-level research consistently related by this series, Volume 16 discusses the ion-exchange isothermal supersaturation technique, metal separation via pH-induced parametric pumping, modeling of ion-exchange kinetics for ultrapure water, ion-exchange.

Ion exchange mechanism. Ion-exchange chromatography which is designed specifically for the separation of differently charged or ionizable compounds comprises from mobile and stationary phases similar to other forms of column based liquid chromatography techniques [].Mobil phases consist an aqueous buffer system into which the mixture to be by: Ion-Exchange Assisted Synthesis of Polymer-Stabilized Metal Nanoparticles,Jorge Macanás, Patricia Ruiz, Amanda Alonso, María Muñoz, and Dmitri N.

Muraviev Ion Exchangers in the Air Purification,V. Soldatov and E. H, Kosandrovich Applications of Selective Ion Exchange for Perchlorate Removal, Recovery, and Environmental Forensics,Baohua Gu, John Karl Böhlke. conventional chelate extraction into an organic solvent.

In this mode, the IL acts simply as a polar nonaqueous solvent. On the other hand, ILs can act as liquid ion exchangers and charged complexes can be extracted into ILs. This is the basis of metal extraction with neutral extractants into the IL extraction phase.

Also in IL. Bruce A. Moyer, Ph.D., has 34 years of experience in R&D on solvent extraction and ion exchange, focusing on metal ion separations for environmental and waste cleanup, nuclear fuel cycles, recovery of critical materials, and national security applications in the USDOE Moyer leads the Chemical Separations Group of ORNL’s (Oak Ridge National Format: Hardcover.

Ion Exchange and Solvent Extraction of Metal Complexes by Yizhak Marcus avg rating — 0 ratings — published Metal-chloride complexes studied by ion exchange and solvent extraction methods. Coordination Chemistry Reviews2 (3), DOI: /S(00) K.W. Bagnall. The coordination chemistry of the actinide by: Automation of Ebook Chromatographic and Ion Exchange Separations for Radiochemical Analysis and Monitoring.

Design Principles and Applications of Centrifugal Contactors for Solvent Extraction. Neoteric Solvents as the Basis of Alternative Approaches to the Separation of Actinides and Fission Products. Index. (source: Nielsen Book Data) Summary.